I know the relationship between temperature and pressure goes as PV=nRT, but then how is this related back to contact patch size and heat of friction generated at the contact patch? I guess I am just a little bit confused on how to think about it since lower tire pressure (from a lower number of moles of gas in the tire before operation) increases the area of the contact patch which increases the chance that a given particle of air inside the tire would hit the (relatively) heated contact patch and "take" some of the contact patch's kinetic energy. In other words, it makes sense that lower tire pressure could increase a tire's average operating temperature since it increases the contact patch area.
As a counterpoint to the above idea, it also makes sense that just putting a greater number of moles of air in the tire before operation (which would decrease contact patch area by making the tire rounder), might also be able to increase temperature, since, even though there is less of a chance for an individual air particle to come in contact with the heated part of the tire, there are more particles.
Is it the case that increasing the number of moles of gas is more effective at hitting the heated contact patch more often (in other words, is increasing the tire pressure before operation better at increasing operating temperature?), or is increasing the contact patch area through a lower initial pressure more effective? I'd assume having more particles in the tire trumps increased contact patch surface area at generating tire heat, but I'm just not sure how to think about it. I guess it's also possible that the answer might depend on the temperatures and pressures in question. Any ideas/help? As a disclaimer, I'm sure this is a relatively rudimentary question, I just don't know that much about tires/gas chemistry.