monsto,I didn´t mean the boiling of the fluid is not of importance,
of course you have to avoid boiling ,especially in the cylinderhead (Hot spots)and you are right boiling water is inhibiting cooling at all...
If the Temp rises above the boiling point you have several choices:increase the cooling area,increase Waterpressure to prevent boiling(limited to 3.75 in F1),increas Airflow thru radiators,increase heat transfer from Engine to cooling medium and back to the radiator itself.
Interestingly enough coolers are in plain aluminium so they throw away the possible additiopnal radiation heat from choosing black matt colour....
actually a brass cooler would ,could transfer heat better as the aluminium if they could avoid soldering the brass ,wich is inhibiting heat transfer and is the only reason why aluminium coolers to dissipate heat better.....
And if you were right that boiling point alone would be of interest so why not use oil instead of water at a boiling point of 130 °C ?Because water has better heat transsfer capabilities the H-bonds in the molecular structure give strong bonds wich let the water boil at a quite high temperature for the size of the molecules ,increasing the pressure strengthens the bonds giving it even more temp capability .That is why Water is so unique for heat transfer.excuse the crude explanation my english has seen better times definitivly