riff_raff wrote:If you accept that "knock" implies spontaneous detonation type combustion ahead of the flame front in an SI engine, then it is not so much time dependent. Instead, it relies more on flame speed, heat transfer, air/fuel mixture, and charge temperatures.
"Knock is the name given to the noise which is transmitted through the engine structure when essentially spontaneous ignition of a portion of the end-gas - the fuel, air, residual gas, mixture ahead of the propagating flame - occurs"
John B. Heywood
End gas temperature and time (along with fuel properties) are the main factors that determine if knock will occur. The higher the end gas temperature, and the longer the time available until the flame front arrives, the more likely is knock to occur.
riff_raff wrote:The peak temperature of the endgas trapped in the quench area is almost entirely determined by heat transfer. The thickness of the endgas volume in the quench area at TDC in a high CR engine is only about 1mm. And it's precisely because this endgas layer is so thin and has a very high rate of heat transfer into the piston crown and cylinder head deck that it inhibits detonation. In fact, this one reason most production auto engines don't use much quench area. The endgas mixture in the quench area never gets hot enough to ignite, so it results in large amounts of unburned HC emissions.
Since the time available for heat transfer is very short, it's impact on the end gas temperature is not that significant.
Here is a plot of the unburned zone temperature, using the GT-Suite simulation software:

As you can see the temperature of the unburned zone is nearly 900 kelvin in this case - well above the self ignition temperature of gasoline - and you can see that the temperature rises rapidly after ignition have occurred just before TDC. You can ignore the rapid jump to 1500 K when the exhaust valve opens.
riff_raff wrote:OK, so technically air/fuel mixtures don't self ignite "instantly". The combustion process requires the correct combination of fuel/oxygen association and (heat) energy input to initiate. But in reality, the constant volume combustion process of HCCI is virtually instantaneous, and it's because of the very rapid heat release rate it produces that it is so thermally efficient. In theory, the HHCI process can be used with any fuel or stoichiometric ratio. But the best efficiency results are achieved with lean mixtures and a detonation resistant fuel. The very rapid constant volume combustion of HCCI also results in much lower peak combustion temperatures, which virtually eliminates any formation of NOx compounds.
You need to separate "combustion process" from "ignition delay". Yes, the HCCI combustion process is very fast due to a lack of a flame and flame propagation, that is why very lean mixtures are used - they slow the combustion process down. But a fast combustion does not mean the fuel will ignite instantly, and with a HCCI engine there is plenty of time to self ignite, usually the whole compression stroke.
HCCI engines are in practice limited to lean mixtures, at richer mixtures they begin to suffer from a type of knocking. The fast burn at richer mixtures will also result in high cylinder pressures/temperatures, and this will increase the heat losses to the cylinder walls. However, since there are few temperature inhomogeneities NOx production is low.
riff_raff wrote:As for combustion in DI CI diesel engines, the ignition delay is dependent upon many factors. The combustion process in a DI diesel engine is no different than that of any other engine. The combustion process will only initiate when there is the proper combination fuel/oxygen association and (heat) energy input. One of the biggest factors in DI diesel ignition delay is the mean droplet size of the fuel spray (Sauter). If you look at the combustion process at the micro level, you'll note that combustion in a DI diesel only occurs at the surface of each fuel droplet, where there is the correct ratio of oxygen and fuel. Plus, the greater mass of large fuel droplets means they take longer to heat up and evaporate. This is critical because only fuel vapor will combust, and not liquid fuel. Thus a well dispersed spray of numerous, very tiny fuel droplets will result in less ignition delay, and will produce faster combustion.
The combustion process of a diesel is different than in a SI or HCCI engine. In a SI engine we have a flame propagation, in the diesel we have a diffusion flame. In the HCCI engine we have no flame at all, but a slow chemical oxidation.
Ignition delay in a diesel is mostly a function of temperature (pressure) and fuel cetane. The following graph shows ignition delay in milliseconds against cylinder pressure at start of combustion. As we can see the ignition delay increase with a reduced pressure (temperature). The data are from measurements on a six cylinder commercial diesel engine.
When you've got a short ignition delay, less fuel will have evaporated before the fuel starts to burn.
WhiteBlue wrote:autogyro wrote:The amount of air in the cylinder is larger with DI, because with port injection the fuel displaces some of the air before it is compressed in the combustion chamber.
I don't think that's the reason. Port injection causes a lot of fuel to stick to the walls instead of going into the mixture. DI wastes no fuel for such purposes. With good DI you my have air excess but no fuel excess. That makes a difference in terms of fuel efficiency.
Autogyro is indeed correct, and that particular effect is described already in NACA papers from the 1940'ties. With port injection some of the air is replaced with fuel vapor, causing a small loss in volumetric efficiency. The cooling offered by the fuel is not enough to compensate for the air displaced by fuel vapor.
The fuel that sticks to the walls in the intake ports is not "wasted" in any way, but it needs to be considered in the control of the engine. This is because fuel sticks to the walls when the pressure is increased, during a load increase for instance, then it leaves the walls when the pressure is decreased, like during a load decrease. This is why the air fuel mixture is enriched during a rapid load increase, and made leaner if the load on the engine rapidly decreases.